http://www.everymac.com/systems/apple/powermac_g5/faq/powermac-g5-superdrive-cdrw-dvd-dvdr-dual-layer-dvd-support.html
here we can see the first official "DL" capable superdrives launched with the powermac g5
2.0 DP (PCI)
2.3 DP (PCI-X)
2.7 DP (PCI-X)
so we see 4x was the first dual layer supported speed
later increased to 6x in second half of year 2005
4X SuperdriveApple reports that this 4X DVD-R/CD-RW SuperDrive "
DVD : writes DVD-R discs at up to 4x speed, reads DVDs at up to 8x speed,
CD : writes CD-R discs at up to16x speed, writes CD-RW discs at up to 10x speed, [and] reads CDs at up to 32x speed."
It uses an Ultra ATA/100 bus.
8X "SuperDrive"Apple reports that this 8X DVD-R/CD-RW SuperDrive "
DVD : writes DVD-R discs at up to 8x speed, reads DVDs at up to 10x speed,
CD : writes CD-R discs at up to 24x speed, writes CD-RW discs at up to 10x speed, [and] reads CDs at up to 32x speed."
It uses an Ultra ATA/100 bus.
4X DL "SuperDrive"Apple reports that this "16X" DVD+R DL/DVD±RW/CD-RW SuperDrive "
DVD: writes DVD-R discs at 16x speed, writes DVD+R DL discs at up to 4x speed, reads DVDs at up to 16x speed,
CD: writes CD-R and CD-RW discs at up to 24x speed and reads CDs at up to 32x speed."
It uses an Ultra ATA/100 bus.
6X DL "SuperDrive"Apple reports that this "16X" DVD+R DL/DVD±RW/CD-RW SuperDrive "
DVD: writes DVD-R discs at 16x speed, writes DVD+R DL discs at up to 6x speed, reads DVDs at up to 16x speed,
CD: writes CD-R and CD-RW discs at up to 24x speed, [and] reads CDs at up to 32x speed."
It uses an Ultra ATA/100 bus.